仲丁醇(chun)(78-92-2)的(de)(de)(de)制(zhi)(zhi)备(bei)(bei)方(fang)(fang)法(fa)(fa)： 本品(pin)由裂解(jie)石油或天然气中(zhong)(zhong)的(de)(de)(de)丁烯于(yu)硫(liu)酸吸(xi)(xi)(xi)(xi)(xi)附后用(yong)(yong)(yong)(yong)水(shui)(shui)(shui)(shui)(shui)(shui)蒸气水(shui)(shui)(shui)(shui)(shui)(shui)解(jie)而得。 储(chu)存方(fang)(fang)法(fa)(fa)： 储(chu)存于(yu)阴凉、通风(feng)(feng)的(de)(de)(de)库房。远离火(huo)(huo)种、热源。库温不(bu)宜超过(guo)37℃。保(bao)持(chi)容器密封。应(ying)与氧(yang)化(hua)剂、酸类(lei)、卤素等分(fen)开存放(fang)，切忌混储(chu)。采用(yong)(yong)(yong)(yong)防(fang)(fang)(fang)爆型(xing)照明、通风(feng)(feng)设(she)施。禁(jin)止(zhi)使(shi)(shi)用(yong)(yong)(yong)(yong)易产生(sheng)火(huo)(huo)花的(de)(de)(de)机械设(she)备(bei)(bei)和(he)(he)工(gong)(gong)具(ju)(ju)。储(chu)区(qu)应(ying)备(bei)(bei)有泄漏(lou)应(ying)急(ji)(ji)处理设(she)备(bei)(bei)和(he)(he)合(he)适的(de)(de)(de)收(shou)容材料(liao)。 鉴别(bie)试(shi)(shi)验：1．溶(rong)解(jie)性(xing)(xing) 易溶(rong)于(yu)水(shui)(shui)(shui)(shui)(shui)(shui)；混溶(rong)于(yu)乙醇(chun)和(he)(he)乙醚。按OT－42方(fang)(fang)法(fa)(fa)测(ce)(ce)定。 2．相对密度(du)(du) 0.806～0.809。 3．应(ying)符合(he)图(tu)19302的(de)(de)(de)红外谱图(tu)。 质(zhi)量(liang)(liang)指标分(fen)析(xi)： 1．酸度(du)(du)(醋酸计(ji)) 取(qu)试(shi)(shi)样60g，加酚酞试(shi)(shi)液(TS－167)数滴，用(yong)(yong)(yong)(yong)0.1mol/L氢氧(yang)化(hua)钾乙醇(chun)液滴定至(zhi)(zhi)出现粉红色(se)，并(bing)维持(chi)15s。耗用(yong)(yong)(yong)(yong)量(liang)(liang)不(bu)得超过(guo)0.3ml。 2．醛和(he)(he)酮(以丁醛计(ji)) 按OT－7方(fang)(fang)法(fa)(fa)测(ce)(ce)定。试(shi)(shi)样量(liang)(liang)取(qu)10g，计(ji)算申的(de)(de)(de)当(dang)量(liang)(liang)因(yin)子(e)取(qu)36.06。 其(qi)它(ta)(ta)： 职业(ye)接触(chu)限值(中(zhong)(zhong)国(guo))未制(zhi)(zhi)定标准职业(ye)接触(chu)限值(美国(guo))TLV-TWA: 100ppm监测(ce)(ce)方(fang)(fang)法(fa)(fa)无资料(liao)工(gong)(gong)程控制(zhi)(zhi)生(sheng)产过(guo)程密闭，全面通风(feng)(feng)。提(ti)供(gong)安(an)全淋浴(yu)和(he)(he)洗(xi)(xi)(xi)眼(yan)(yan)设(she)备(bei)(bei)呼(hu)吸(xi)(xi)(xi)(xi)(xi)系统(tong)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)一(yi)(yi)般(ban)不(bu)需(xu)要(yao)特(te)(te)殊防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)，高浓度(du)(du)接触(chu)时可佩(pei)戴(dai)(dai)过(guo)滤式(shi)防(fang)(fang)(fang)毒面具(ju)(ju)(半(ban)面罩)眼(yan)(yan)睛(jing)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)戴(dai)(dai)安(an)全防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)眼(yan)(yan)镜身体防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)穿(chuan)防(fang)(fang)(fang)静(jing)电(dian)工(gong)(gong)作服(fu)手(shou)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)戴(dai)(dai)一(yi)(yi)般(ban)作业(ye)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)手(shou)套其(qi)它(ta)(ta)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)工(gong)(gong)作现场(chang)(chang)严(yan)禁(jin)吸(xi)(xi)(xi)(xi)(xi)烟。保(bao)持(chi)良(liang)好(hao)的(de)(de)(de)卫(wei)(wei)生(sheng)习(xi)惯。 毒性(xing)(xing)： 急(ji)(ji)性(xing)(xing)毒性(xing)(xing)LD50：2193mg/kg(大(da)鼠经(jing)口)；4893mg/kg(兔经(jing)口)；>2000mg/kg(大(da)鼠经(jing)皮(pi))刺激性(xing)(xing)家兔经(jing)皮(pi)：500mg(24h)，轻(qing)度(du)(du)刺激。家兔经(jing)眼(yan)(yan)：100mg(24h)，中(zhong)(zhong)度(du)(du)刺激其(qi)它(ta)(ta)大(da)鼠吸(xi)(xi)(xi)(xi)(xi)入最低中(zhong)(zhong)毒浓度(du)(du)(TCLo)：5000ppm/7h(孕1～19d)，致胚胎毒性(xing)(xing)。生(sheng)态毒性(xing)(xing)LD50：4300mg/L(24h)(金鱼(yu))。IC50：312mg/L(72h)(藻类(lei))生(sheng)物(wu)降(jiang)解(jie)性(xing)(xing)好(hao)氧(yang)生(sheng)物(wu)降(jiang)解(jie)(h)：24～168。厌氧(yang)生(sheng)物(wu)降(jiang)解(jie)(h)：96～672非生(sheng)物(wu)降(jiang)解(jie)性(xing)(xing)水(shui)(shui)(shui)(shui)(shui)(shui)中(zhong)(zhong)光氧(yang)化(hua)半(ban)衰期(qi)(h)：3100～1.00×106。空气中(zhong)(zhong)光氧(yang)化(hua)半(ban)衰期(qi)(h)：7.2～72。废(fei)(fei)弃(qi)物(wu)性(xing)(xing)质(zhi)危险(xian)废(fei)(fei)物(wu)废(fei)(fei)弃(qi)处置方(fang)(fang)法(fa)(fa)建(jian)议(yi)(yi)用(yong)(yong)(yong)(yong)焚烧法(fa)(fa)处置废(fei)(fei)弃(qi)注意事项处置前应(ying)参(can)阅国(guo)家和(he)(he)地(di)方(fang)(fang)有关(guan)法(fa)(fa)规。 泄漏(lou)应(ying)急(ji)(ji)处理：迅(xun)速撤(che)离泄漏(lou)污染区(qu)人(ren)员(yuan)至(zhi)(zhi)安(an)全区(qu)，并(bing)进(jin)行(xing)隔离，严(yan)格限制(zhi)(zhi)出入。切断火(huo)(huo)源。建(jian)议(yi)(yi)应(ying)急(ji)(ji)处理人(ren)员(yuan)戴(dai)(dai)自给正压式(shi)呼(hu)吸(xi)(xi)(xi)(xi)(xi)器，穿(chuan)消防(fang)(fang)(fang)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)服(fu)。尽可能切断泄漏(lou)源。防(fang)(fang)(fang)止(zhi)进(jin)入下(xia)水(shui)(shui)(shui)(shui)(shui)(shui)道(dao)、排洪沟等限制(zhi)(zhi)性(xing)(xing)空间。小量(liang)(liang)泄漏(lou)：用(yong)(yong)(yong)(yong)活性(xing)(xing)炭(tan)或其(qi)它(ta)(ta)惰性(xing)(xing)材料(liao)吸(xi)(xi)(xi)(xi)(xi)收(shou)。也(ye)可以用(yong)(yong)(yong)(yong)大(da)量(liang)(liang)水(shui)(shui)(shui)(shui)(shui)(shui)冲洗(xi)(xi)(xi)，洗(xi)(xi)(xi)水(shui)(shui)(shui)(shui)(shui)(shui)稀(xi)释后放(fang)入废(fei)(fei)水(shui)(shui)(shui)(shui)(shui)(shui)系统(tong)。大(da)量(liang)(liang)泄漏(lou)：构筑围堤或挖(wa)坑收(shou)容；用(yong)(yong)(yong)(yong)泡(pao)沫(mo)覆盖，降(jiang)低蒸气灾害(hai)。用(yong)(yong)(yong)(yong)防(fang)(fang)(fang)爆泵转至(zhi)(zhi)槽车或专用(yong)(yong)(yong)(yong)收(shou)集器内，回(hui)收(shou)或运至(zhi)(zhi)废(fei)(fei)物(wu)处理场(chang)(chang)所处置。 防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)措施： 1.呼(hu)吸(xi)(xi)(xi)(xi)(xi)系统(tong)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)：一(yi)(yi)般(ban)不(bu)需(xu)要(yao)特(te)(te)殊防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)，高浓度(du)(du)接触(chu)时可佩(pei)戴(dai)(dai)自吸(xi)(xi)(xi)(xi)(xi)过(guo)滤式(shi)防(fang)(fang)(fang)毒面具(ju)(ju)(半(ban)面罩)。 2.眼(yan)(yan)睛(jing)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)：戴(dai)(dai)安(an)全防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)眼(yan)(yan)镜。 3.身体防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)：穿(chuan)防(fang)(fang)(fang)静(jing)电(dian)工(gong)(gong)作服(fu)。 4.手(shou)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)：戴(dai)(dai)一(yi)(yi)般(ban)作业(ye)防(fang)(fang)(fang)护(hu)(hu)(hu)(hu)(hu)(hu)手(shou)套。 5.其(qi)它(ta)(ta)：工(gong)(gong)作现场(chang)(chang)严(yan)禁(jin)吸(xi)(xi)(xi)(xi)(xi)烟。保(bao)持(chi)良(liang)好(hao)的(de)(de)(de)卫(wei)(wei)生(sheng)习(xi)惯。 急(ji)(ji)救措施： 1.皮(pi)肤接触(chu)：脱去被(bei)污染的(de)(de)(de)衣(yi)着，用(yong)(yong)(yong)(yong)肥皂水(shui)(shui)(shui)(shui)(shui)(shui)和(he)(he)清水(shui)(shui)(shui)(shui)(shui)(shui)彻(che)底(di)冲洗(xi)(xi)(xi)皮(pi)肤。就医。 2.眼(yan)(yan)睛(jing)接触(chu)：立即提(ti)起(qi)眼(yan)(yan)睑，用(yong)(yong)(yong)(yong)大(da)量(liang)(liang)流动(dong)清水(shui)(shui)(shui)(shui)(shui)(shui)或生(sheng)理盐水(shui)(shui)(shui)(shui)(shui)(shui)彻(che)底(di)冲洗(xi)(xi)(xi)至(zhi)(zhi)少15分(fen)钟。就医。 3.吸(xi)(xi)(xi)(xi)(xi)入：迅(xun)速脱离现场(chang)(chang)至(zhi)(zhi)空气新(xin)鲜处。保(bao)持(chi)呼(hu)吸(xi)(xi)(xi)(xi)(xi)道(dao)通畅。如(ru)呼(hu)吸(xi)(xi)(xi)(xi)(xi)困难，给输氧(yang)。如(ru)呼(hu)吸(xi)(xi)(xi)(xi)(xi)停止(zhi)时，立即进(jin)行(xing)人(ren)工(gong)(gong)呼(hu)吸(xi)(xi)(xi)(xi)(xi)。就医。 4.食(shi)入：饮足量(liang)(liang)温水(shui)(shui)(shui)(shui)(shui)(shui)，催吐。就医。 5.灭火(huo)(huo)方(fang)(fang)法(fa)(fa)：用(yong)(yong)(yong)(yong)雾状(zhuang)水(shui)(shui)(shui)(shui)(shui)(shui)保(bao)持(chi)火(huo)(huo)场(chang)(chang)容器冷却，用(yong)(yong)(yong)(yong)水(shui)(shui)(shui)(shui)(shui)(shui)喷射逸出液体，使(shi)(shi)其(qi)稀(xi)释成不(bu)燃性(xing)(xing)混合(he)物(wu)，并(bing)用(yong)(yong)(yong)(yong)雾状(zhuang)水(shui)(shui)(shui)(shui)(shui)(shui)保(bao)护(hu)(hu)(hu)(hu)(hu)(hu)消防(fang)(fang)(fang)人(ren)员(yuan)。灭火(huo)(huo)剂：抗溶(rong)性(xing)(xing)泡(pao)沫(mo)、干粉、二(er)氧(yang)化(hua)碳、雾状(zhuang)水(shui)(shui)(shui)(shui)(shui)(shui)、1211灭火(huo)(huo)剂、砂土(tu)。